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銅触媒を用いた炭素求核剤のオレフィンへの付加反応
https://doi.org/10.14988/pa.2017.0000011306
https://doi.org/10.14988/pa.2017.0000011306503d80bd-18dd-4324-98f1-68354ba07a92
名前 / ファイル | ライセンス | アクション |
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023048040001.pdf (371.0 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||||
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公開日 | 2008-02-06 | |||||||||||
タイトル | ||||||||||||
言語 | ja | |||||||||||
タイトル | 銅触媒を用いた炭素求核剤のオレフィンへの付加反応 | |||||||||||
タイトル | ||||||||||||
言語 | ja-Kana | |||||||||||
タイトル | ドウ ショクバイ オ モチイタ タンソ キュウカクザイ ノ オレフィン エノ フカ ハンノウ | |||||||||||
タイトル | ||||||||||||
言語 | en | |||||||||||
タイトル | Copper-Catalyzed Addition Reaction of Carbon Nucleophiles to Olefins | |||||||||||
言語 | ||||||||||||
言語 | jpn | |||||||||||
キーワード | ||||||||||||
主題 | 炭素求核剤, オレフィン, 銅, ケト-エノール互変異性 carbon nucleophile, olefin, copper, keto-enol tautomerism |
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資源タイプ | ||||||||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||||
資源タイプ | departmental bulletin paper | |||||||||||
ID登録 | ||||||||||||
ID登録 | 10.14988/pa.2017.0000011306 | |||||||||||
ID登録タイプ | JaLC | |||||||||||
アクセス権 | ||||||||||||
アクセス権 | open access | |||||||||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
著者 |
新川, 慶
× 新川, 慶× 大西, 紀子× 宮本, 崇史× 太田, 哲男× 伊藤, 嘉彦
WEKO
15783
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著者所属 | ||||||||||||
ja | ||||||||||||
新川, 慶 / Department of Molecular Science and Technology, Doshisha University | ||||||||||||
著者所属 | ||||||||||||
ja | ||||||||||||
大西, 紀子 / Department of Molecular Science and Technology, Doshisha University | ||||||||||||
著者所属 | ||||||||||||
ja | ||||||||||||
宮本, 崇史 / Department of Molecular Science and Technology, Doshisha University | ||||||||||||
著者所属 | ||||||||||||
ja | ||||||||||||
太田, 哲男 / Department of Molecular Science and Technology, Doshisha University | ||||||||||||
著者所属 | ||||||||||||
ja | ||||||||||||
伊藤, 嘉彦 / 元同志社大学客員教授 | ||||||||||||
著者所属(英) | ||||||||||||
en | ||||||||||||
Doshisha University | ||||||||||||
所属機関識別子種別 | ||||||||||||
値 | kakenhi | |||||||||||
所属機関識別子 | ||||||||||||
値 | 34310 | |||||||||||
抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | 炭素求核剤のオレフィンへの付加反応を銅を触媒に用いて検討した。例えば、ジベンゾイルメタン(2a)とスチレン(1a)の反応は、Cu(OTf)₂触媒存在下、ベンゼン中70℃24時間で1,3-ジフェニル-2-(1-フェニルエチル)プロパン-1,3-ジオン(3aa)を95%の収率で与える。この反応は各種β-ジカルボニル化合物やジエンを含むオレフィンに適用可能である。さらに、反応機構も提案した。 | |||||||||||
言語 | ja | |||||||||||
抄録 | ||||||||||||
内容記述タイプ | Abstract | |||||||||||
内容記述 | Addition reaction of carbon nucleophiles to olefins was studied using copper as a catalyst. For example, reaction of dibenzoylmethane (2a) with styrene (1a) in the presence of Cu(OTf)₂ catalyst at 70℃ for 24 h in benzene gave 1,3-diphenyl-2-(1-phenylethyl)propane-1,3-dione (3aa) in 95% yield. This reaction was able to be applied for various β-dicarbonyl compounds and olefins including diene. Furthermore, reaction mechanism was proposed. | |||||||||||
言語 | en | |||||||||||
書誌情報 |
ja : 同志社大学理工学研究報告 en : The Science and Engineering Review of Doshisha University 巻 48, 号 4, p. [221]-227, 発行日 2008-01-31 |
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出版者 | ||||||||||||
言語 | ja | |||||||||||
出版者 | 同志社大学理工学研究所 | |||||||||||
出版者(英) | ||||||||||||
言語 | en | |||||||||||
出版者 | Science and Engineering Research Institute of Doshisha University | |||||||||||
ISSN | ||||||||||||
収録物識別子タイプ | PISSN | |||||||||||
収録物識別子 | 00368172 | |||||||||||
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収録物識別子タイプ | NCID | |||||||||||
収録物識別子 | AN00165868 | |||||||||||
権利者情報 | ||||||||||||
権利者名 | 同志社大学理工学研究所 | |||||||||||
言語 | ja | |||||||||||
権利者名 | Science and Engineering Research Institute of Doshisha University | |||||||||||
言語 | en | |||||||||||
関連サイト | ||||||||||||
関連タイプ | isFormatOf | |||||||||||
識別子タイプ | URI | |||||||||||
関連識別子 | https://doors.doshisha.ac.jp/opac/opac_link/bibid/SB00960326/?lang=0 | |||||||||||
言語 | ja | |||||||||||
関連名称 | 掲載刊行物所蔵情報へのリンク / Link to Contents | |||||||||||
フォーマット | ||||||||||||
内容記述タイプ | Other | |||||||||||
内容記述 | application/pdf | |||||||||||
出版タイプ | ||||||||||||
出版タイプ | VoR | |||||||||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||||||||
日本十進分類法 | ||||||||||||
主題 | 437 |