{"created":"2023-07-27T07:45:49.304031+00:00","id":20113,"links":{},"metadata":{"_buckets":{"deposit":"f583c984-3c16-4629-b77e-ab532601a6bb"},"_deposit":{"created_by":20,"id":"20113","owners":[20],"pid":{"revision_id":0,"type":"depid","value":"20113"},"status":"published"},"_oai":{"id":"oai:doshisha.repo.nii.ac.jp:00020113","sets":["4251:8393:8394:8395:8424","8:3372:3812:3841"]},"author_link":["15779","15780","15781","15782","15783"],"item_1693811493084":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1694490770713":{"attribute_name":"権利者情報","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"DA03974933","nameIdentifierScheme":"AID"}],"rightHolderNames":[{"rightHolderLanguage":"ja","rightHolderName":"同志社大学理工学研究所"},{"rightHolderLanguage":"en","rightHolderName":"Science and Engineering Research Institute of Doshisha University"}]}]},"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2008-01-31","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"4","bibliographicPageEnd":"227","bibliographicPageStart":"[221]","bibliographicVolumeNumber":"48","bibliographic_titles":[{"bibliographic_title":"同志社大学理工学研究報告","bibliographic_titleLang":"ja"},{"bibliographic_title":"The Science and Engineering Review of Doshisha University","bibliographic_titleLang":"en"}]}]},"item_1_description_12":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"炭素求核剤のオレフィンへの付加反応を銅を触媒に用いて検討した。例えば、ジベンゾイルメタン(2a)とスチレン(1a)の反応は、Cu(OTf)₂触媒存在下、ベンゼン中70℃24時間で1,3-ジフェニル-2-(1-フェニルエチル)プロパン-1,3-ジオン(3aa)を95%の収率で与える。この反応は各種β-ジカルボニル化合物やジエンを含むオレフィンに適用可能である。さらに、反応機構も提案した。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"Addition reaction of carbon nucleophiles to olefins was studied using copper as a catalyst. For example, reaction of dibenzoylmethane (2a) with styrene (1a) in the presence of Cu(OTf)₂ catalyst at 70℃ for 24 h in benzene gave 1,3-diphenyl-2-(1-phenylethyl)propane-1,3-dione (3aa) in 95% yield. This reaction was able to be applied for various β-dicarbonyl compounds and olefins including diene. Furthermore, reaction mechanism was proposed.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_1_description_25":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_1_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.14988/pa.2017.0000011306","subitem_identifier_reg_type":"JaLC"}]},"item_1_publisher_15":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"同志社大学理工学研究所","subitem_publisher_language":"ja"}]},"item_1_publisher_16":{"attribute_name":"出版者（英）","attribute_value_mlt":[{"subitem_publisher":"Science and Engineering Research Institute of Doshisha University","subitem_publisher_language":"en"}]},"item_1_relation_24":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"掲載刊行物所蔵情報へのリンク ／ Link to 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Department of Molecular Science and Technology, Doshisha University"},{"subitem_text_language":"ja","subitem_text_value":"大西, 紀子 / Department of Molecular Science and Technology, Doshisha University"},{"subitem_text_language":"ja","subitem_text_value":"宮本, 崇史 / Department of Molecular Science and Technology, Doshisha University"},{"subitem_text_language":"ja","subitem_text_value":"太田, 哲男 / Department of Molecular Science and Technology, Doshisha University"},{"subitem_text_language":"ja","subitem_text_value":"伊藤, 嘉彦 / 元同志社大学客員教授"}]},"item_1_text_9":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Doshisha University"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"新川, 慶","creatorNameLang":"ja"},{"creatorName":"ニイガワ, ケイ","creatorNameLang":"ja-Kana"},{"creatorName":"Niigawa, Kei","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"大西, 紀子","creatorNameLang":"ja"},{"creatorName":"オオニシ, ノリコ","creatorNameLang":"ja-Kana"},{"creatorName":"Ohnishi, Noriko","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"宮本, 崇史","creatorNameLang":"ja"},{"creatorName":"ミヤモト, タカシ","creatorNameLang":"ja-Kana"},{"creatorName":"Miyamoto, Takashi","creatorNameLang":"en"}],"nameIdentifiers":[{},{}]},{"creatorNames":[{"creatorName":"太田, 哲男","creatorNameLang":"ja"},{"creatorName":"オオタ, テツオ","creatorNameLang":"ja-Kana"},{"creatorName":"Ohta, Tetsuo","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]},{"creatorNames":[{"creatorName":"伊藤, 嘉彦","creatorNameLang":"ja"},{"creatorName":"イトウ, ヨシヒコ","creatorNameLang":"ja-Kana"},{"creatorName":"Ito, Yoshihiko","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2008-04-15"}],"displaytype":"detail","filename":"023048040001.pdf","filesize":[{"value":"371.0 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"023048040001.pdf","url":"https://doshisha.repo.nii.ac.jp/record/20113/files/023048040001.pdf"},"version_id":"299647e5-caa5-419a-9d11-e0638b8d26fc"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"炭素求核剤","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"オレフィン","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"銅","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"ケト-エノール互変異性","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"carbon nucleophile","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"olefin","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"copper","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"keto-enol tautomerism","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"銅触媒を用いた炭素求核剤のオレフィンへの付加反応","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"銅触媒を用いた炭素求核剤のオレフィンへの付加反応","subitem_title_language":"ja"},{"subitem_title":"ドウ ショクバイ オ モチイタ タンソ キュウカクザイ ノ オレフィン エノ フカ ハンノウ","subitem_title_language":"ja-Kana"},{"subitem_title":"Copper-Catalyzed Addition Reaction of Carbon Nucleophiles to Olefins","subitem_title_language":"en"}]},"item_type_id":"1","owner":"20","path":["3841","8424"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2008-02-06"},"publish_date":"2008-02-06","publish_status":"0","recid":"20113","relation_version_is_last":true,"title":["銅触媒を用いた炭素求核剤のオレフィンへの付加反応"],"weko_creator_id":"20","weko_shared_id":-1},"updated":"2023-11-30T07:03:36.827996+00:00"}