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原子効率に優れたアリルアルコール類の新規触媒的分子変換法に関する研究
https://doi.org/10.14988/di.2017.0000016959
https://doi.org/10.14988/di.2017.0000016959cc90667e-da93-4e09-93b1-458b52616d2e
名前 / ファイル | ライセンス | アクション |
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要旨/abstaract (445.1 kB)
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zk854.pdf (1.7 MB)
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Item type | 学位論文 / Thesis or Dissertation(1) | |||||
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公開日 | 2017-04-27 | |||||
タイトル | ||||||
言語 | ja | |||||
タイトル | 原子効率に優れたアリルアルコール類の新規触媒的分子変換法に関する研究 | |||||
タイトル | ||||||
言語 | ja-Kana | |||||
タイトル | ゲンシ コウリツ ニ スグレタ アリル アルコールルイ ノ シンキ ショクバイテキ ブンシ ヘンカンホウ ニカンスル ケンキュウ | |||||
言語 | ||||||
言語 | jpn | |||||
キーワード | ||||||
主題 | 触媒, アリルアルコール類, 原子効率, ルテニウム, 水素移動 catalyst, allylic alcohols, atom economy, ruthenium, borrowing hydrogen |
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資源タイプ | ||||||
資源タイプ識別子 | http://purl.org/coar/resource_type/c_db06 | |||||
資源タイプ | doctoral thesis | |||||
ID登録 | ||||||
ID登録 | 10.14988/di.2017.0000016959 | |||||
ID登録タイプ | JaLC | |||||
アクセス権 | ||||||
アクセス権 | open access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_abf2 | |||||
著者 |
中村, 祐士
× 中村, 祐士 |
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著者所属 | ||||||
ja | ||||||
生命医科学研究科 | ||||||
著者所属(英) | ||||||
en | ||||||
Graduate School of Life and Medical Sciences | ||||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 遷移金属錯体を触媒とした原子効率に優れたアリルアルコール類の新規変換法の開発について検討した。アリルアルコール類のアルコールとしての性質に着目し、主に"Borrowing hydrogen"方法論に基づいた反応開発について検討した結果, 独自に調製された高度な水素移動制御を可能とするルテニウム触媒を用いることで、原子効率100%のアリルアルコール類のanti-Markovnikov型ヒドロアミノ化反応やヒドロアルコキシ化を始めとした反応の開発に成功した。 | |||||
言語 | ja | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | Development of novel transform methods of allylic alcohols catalyzed by transition metal complexes was studied. In the result, development of anti-Markovnikov hydroamination and hydroalkoxylation of allylic alcohols catalyzed by uniquely prepared ruthenium catalysts, which had a advanced transfer hydrogen ability, on the basis of a character as a alcohol of allylic alcohols and "Borrowing hydrogen" methodology was achieved at 100% atom economy. | |||||
言語 | en | |||||
書誌レコードID | ||||||
識別子タイプ | NCID | |||||
関連識別子 | BB25875867 | |||||
関連サイト | ||||||
関連タイプ | isFormatOf | |||||
識別子タイプ | URI | |||||
関連識別子 | https://doors.doshisha.ac.jp/opac/opac_link/bibid/BB13045024/?lang=0 | |||||
言語 | ja | |||||
関連名称 | 掲載刊行物所蔵情報へのリンク / Link to Contents | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
出版タイプ | ||||||
出版タイプ | VoR | |||||
出版タイプResource | http://purl.org/coar/version/c_970fb48d4fbd8a85 | |||||
学位名 | ||||||
言語 | ja | |||||
学位名 | 博士(工学) | |||||
学位名(英) | ||||||
言語 | en | |||||
学位名 | Doctor of Philosophy in Engineering | |||||
学位授与機関 | ||||||
学位授与機関識別子Scheme | kakenhi | |||||
学位授与機関識別子 | 34310 | |||||
言語 | ja | |||||
学位授与機関名 | 同志社大学 | |||||
言語 | en | |||||
学位授与機関名 | Doshisha University | |||||
学位授与年月日 | ||||||
学位授与年月日 | 2017-03-22 | |||||
学位授与番号 | ||||||
学位授与番号 | 甲第854号 |