{"created":"2023-07-27T07:30:38.008382+00:00","id":1363,"links":{},"metadata":{"_buckets":{"deposit":"78e89413-1afd-40ee-9591-900216a02b84"},"_deposit":{"created_by":20,"id":"1363","owners":[20],"pid":{"revision_id":0,"type":"depid","value":"1363"},"status":"published"},"_oai":{"id":"oai:doshisha.repo.nii.ac.jp:00001363","sets":["4151:8699:4190:4191","4251:7209:7210:8775:7211"]},"author_link":["3001"],"item_1693813220986":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1694497428290":{"attribute_name":"学位名","attribute_value_mlt":[{"subitem_degreename":"博士(工学)","subitem_degreename_language":"ja"}]},"item_1694497507610":{"attribute_name":"学位名(英)","attribute_value_mlt":[{"subitem_degreename":"Doctor of Philosophy in Engineering","subitem_degreename_language":"en"}]},"item_1694497573527":{"attribute_name":"学位授与機関","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_language":"ja","subitem_degreegrantor_name":"同志社大学"},{"subitem_degreegrantor_language":"en","subitem_degreegrantor_name":"Doshisha University"}],"subitem_degreegrantor_identifier":[{"subitem_degreegrantor_identifier_name":"34310","subitem_degreegrantor_identifier_scheme":"kakenhi"}]}]},"item_3_date_granted_27":{"attribute_name":"学位授与年月日","attribute_value_mlt":[{"subitem_dategranted":"2017-03-22"}]},"item_3_description_12":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"遷移金属錯体を触媒とした原子効率に優れたアリルアルコール類の新規変換法の開発について検討した。アリルアルコール類のアルコールとしての性質に着目し、主に\"Borrowing hydrogen\"方法論に基づいた反応開発について検討した結果, 独自に調製された高度な水素移動制御を可能とするルテニウム触媒を用いることで、原子効率100%のアリルアルコール類のanti-Markovnikov型ヒドロアミノ化反応やヒドロアルコキシ化を始めとした反応の開発に成功した。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"Development of novel transform methods of allylic alcohols catalyzed by transition metal complexes was studied. In the result, development of anti-Markovnikov hydroamination and hydroalkoxylation of allylic alcohols catalyzed by uniquely prepared ruthenium catalysts, which had a advanced transfer hydrogen ability, on the basis of a character as a alcohol of allylic alcohols and \"Borrowing hydrogen\" methodology was achieved at 100% atom economy.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_18":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_dissertation_number_28":{"attribute_name":"学位授与番号","attribute_value_mlt":[{"subitem_dissertationnumber":"甲第854号"}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.14988/di.2017.0000016959","subitem_identifier_reg_type":"JaLC"}]},"item_3_relation_16":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"BB25875867","subitem_relation_type_select":"NCID"}}]},"item_3_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"掲載刊行物所蔵情報へのリンク / Link to 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Yushi","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"3001","nameIdentifierScheme":"WEKO"},{"nameIdentifier":"9000345253879","nameIdentifierScheme":"CiNii ID","nameIdentifierURI":"http://ci.nii.ac.jp/nrid/9000345253879"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-04-14"}],"displaytype":"detail","filename":"k854.pdf","filesize":[{"value":"445.1 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"要旨/abstaract","objectType":"abstract","url":"https://doshisha.repo.nii.ac.jp/record/1363/files/k854.pdf"},"version_id":"b600905d-ce82-4bdd-bb69-d2b751083513"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2018-03-01"}],"displaytype":"detail","filename":"zk854.pdf","filesize":[{"value":"1.7 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"zk854.pdf","objectType":"fulltext","url":"https://doshisha.repo.nii.ac.jp/record/1363/files/zk854.pdf"},"version_id":"d795e2bf-d9be-4236-855a-1d3a6833d820"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"触媒","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"アリルアルコール類","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"原子効率","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"ルテニウム","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"水素移動","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"catalyst","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"allylic alcohols","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"atom economy","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"ruthenium","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"borrowing hydrogen","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"doctoral thesis","resourceuri":"http://purl.org/coar/resource_type/c_db06"}]},"item_title":"原子効率に優れたアリルアルコール類の新規触媒的分子変換法に関する研究","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"原子効率に優れたアリルアルコール類の新規触媒的分子変換法に関する研究","subitem_title_language":"ja"},{"subitem_title":"ゲンシ コウリツ ニ スグレタ アリル アルコールルイ ノ シンキ ショクバイテキ ブンシ ヘンカンホウ ニカンスル ケンキュウ ","subitem_title_language":"ja-Kana"}]},"item_type_id":"3","owner":"20","path":["4191","7211"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2017-04-27"},"publish_date":"2017-04-27","publish_status":"0","recid":"1363","relation_version_is_last":true,"title":["原子効率に優れたアリルアルコール類の新規触媒的分子変換法に関する研究"],"weko_creator_id":"20","weko_shared_id":-1},"updated":"2023-12-20T07:06:10.024531+00:00"}