@article{oai:doshisha.repo.nii.ac.jp:00029320,
 author = {渡邉, 玲 and Watanabe, Rei and 木村, 佳文 and Kimura, Yoshifumi},
 issue = {3},
 journal = {同志社大学ハリス理化学研究報告, The Harris science review of Doshisha University},
 month = {Oct},
 note = {1-Methylimidazolium triflate([HMIM][TfO])は常温で固体であり、85℃で相転移をおこない柔粘性結晶となる。[HMIM][TfO]に6-hydroxyquinolineや2-aminopyrizineをドープした蛍光測定の結果から、固相や柔粘性結晶中で[HMIM][TfO]のプロトン供与性が非常に高いことがわかった。一方でtrisodium 8-hydroxypyrene-1,3,6-trisulfonate(HPTS)をドープしたところ、そのままではプロトン移動は起こらないが1-methylimidazole(MIM)を添加すると固相で会合体を生成し、HTPSからMIMへプロトン移動が生じることが明らかとなった。一方柔粘性結晶相では、分子の自由回転のために会合体が消失し特有のプロトン移動は起こらないことが分かった。, Proton transfer reactions of various photoacids or photobases in 1-methylimidazolium triflate ([HMIM][TfO]) has been studied by steady-state fluorescence spectroscopy and time-resolved fluorescence spectroscopy. The fluorescence and excitation spectra of 2-aminopyridine and 6-hydroxyquinoline indicated a high acidity of [HMIM][TfO]. We also observed the proton transfer from trisodium 8-hydroxypyrene-1,3,6-trisulfonate (HPTS) to 1-methylimidazole (MIM) or water added to [HMIM][TfO] as co-solvent. The fluorescence excitation spectra indicated that the existence of the complex between HPTS and MIM. The fluorescence dynamics indicated that the site selective proton transfer occurred in solid [HMIM][TfO]. In a PC phase, such an unique process was not observed, suggesting that the rotational dynamics in PC was similar to that in liquids phase., application/pdf},
 pages = {163--171},
 title = {イオン性柔粘性結晶中でのプロトン移動反応の評価},
 volume = {63},
 year = {2022},
 yomi = {ワタナベ, レイ and キムラ, ヨシフミ}
}