{"created":"2023-07-27T07:52:37.854577+00:00","id":28184,"links":{},"metadata":{"_buckets":{"deposit":"1024f988-273d-472c-bf5e-17be32d90a38"},"_deposit":{"created_by":20,"id":"28184","owners":[20],"pid":{"revision_id":0,"type":"depid","value":"28184"},"status":"published"},"_oai":{"id":"oai:doshisha.repo.nii.ac.jp:00028184","sets":["4151:8699:4187:4189","4251:7205:7206:8773:7208"]},"author_link":["28852"],"item_1693813220986":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1694497428290":{"attribute_name":"学位名","attribute_value_mlt":[{"subitem_degreename":"博士(理学)","subitem_degreename_language":"ja"}]},"item_1694497507610":{"attribute_name":"学位名（英）","attribute_value_mlt":[{"subitem_degreename":"Doctor of Philosophy in Science","subitem_degreename_language":"en"}]},"item_1694497573527":{"attribute_name":"学位授与機関","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_language":"ja","subitem_degreegrantor_name":"同志社大学"},{"subitem_degreegrantor_language":"en","subitem_degreegrantor_name":"Doshisha University"}],"subitem_degreegrantor_identifier":[{"subitem_degreegrantor_identifier_name":"34310","subitem_degreegrantor_identifier_scheme":"kakenhi"}]}]},"item_3_alternative_title_2":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"時間分解分光法による化学反応素過程の研究 : 超臨界流体からイオン液体まで","subitem_alternative_title_language":"ja"},{"subitem_alternative_title":"ジカン ブンカイ ブンコウホウ ニヨル カガク ハンノウ ソカテイ ノ ケンキュウ : チョウリンカイ リュウタイ カラ イオン エキタイ マデ","subitem_alternative_title_language":"ja-Kana"}]},"item_3_date_granted_27":{"attribute_name":"学位授与年月日","attribute_value_mlt":[{"subitem_dategranted":"2021-03-22"}]},"item_3_description_12":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"多数の溶媒分子に取り囲まれている溶液中において溶質分子の化学反応素過程を考える場合、溶媒分子による反応の平衡論的、動的な効果を考える必要がある。本研究では、ユニークな反応場として水や有機溶媒とは区別される、超臨界流体とイオン液体をとり上げ、溶質分子のプロトン移動反応、光解離反応について、時間分解レーザー分光と分子動力学計算、理論的解析を行い、その現象を明らかにする試みをおこなった。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"In solution, solvent molecules involve chemical reaction of solute molecules and could alter both reaction yield and kinetics. In this thesis, the author focused on fundamental chemical reactions (intermolecular proton transfer and photodissociate reaction) in a unique class of solvents, supercritical fluids and ionic liquids. By measuring time-resolved fluorescence spectrum and transient absorption spectrum of solutes, the author discusses how the reaction yield and kinetics are described by solvent physicochemical properties.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_18":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_dissertation_number_28":{"attribute_name":"学位授与番号","attribute_value_mlt":[{"subitem_dissertationnumber":"甲第1159号"}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.14988/00028176","subitem_identifier_reg_type":"JaLC"}]},"item_3_relation_16":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"BC08625259","subitem_relation_type_select":"NCID"}}]},"item_3_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"掲載刊行物所蔵情報へのリンク ／ Link to 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Kaori","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2021-05-17"}],"displaytype":"detail","filename":"k1159.pdf","filesize":[{"value":"473.8 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"要旨/abstaract","objectType":"abstract","url":"https://doshisha.repo.nii.ac.jp/record/28184/files/k1159.pdf"},"version_id":"09238d7f-3c03-4566-8eaa-ed94cb3ee01a"},{"accessrole":"open_access","displaytype":"detail","filename":"zk1159.pdf","filesize":[{"value":"6.0 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://doshisha.repo.nii.ac.jp/record/28184/files/zk1159.pdf"},"version_id":"66ad3970-457f-4904-b5ba-e63a4b647565"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"イオン液体","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"超臨界メタノール","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"時間分解蛍光スペクトル","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"過渡吸収スペクトル","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"励起状態プロトン移動反応","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"光解離反応","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"溶媒和ダイナミクス","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"分子動力学計算","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"拡散律速反応","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"Ioinic liquids","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Supercritical methanol","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Time-resolved fluorescence spectrum","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Transient absorption spectrum","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Excited state intermolecular proton transfer","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Photodissociation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Solvation dynamics","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Molecular dynamics simulation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Diffusion limited reaction","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"doctoral thesis","resourceuri":"http://purl.org/coar/resource_type/c_db06"}]},"item_title":"Time-resolved spectroscopic study on fundamental chemical reactions in a unique class of solvents","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Time-resolved spectroscopic study on fundamental chemical reactions in a unique class of solvents","subitem_title_language":"en"}]},"item_type_id":"3","owner":"20","path":["4189","7208"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2021-05-17"},"publish_date":"2021-05-17","publish_status":"0","recid":"28184","relation_version_is_last":true,"title":["Time-resolved spectroscopic study on fundamental chemical reactions in a unique class of solvents"],"weko_creator_id":"20","weko_shared_id":-1},"updated":"2023-12-20T07:14:53.186191+00:00"}