{"created":"2024-04-24T07:13:02.988919+00:00","id":2000446,"links":{},"metadata":{"_buckets":{"deposit":"617ddd23-6ea6-4435-ac03-9fb14b662632"},"_deposit":{"created_by":20,"id":"2000446","owners":[20],"pid":{"revision_id":0,"type":"depid","value":"2000446"},"status":"published"},"_oai":{"id":"oai:doshisha.repo.nii.ac.jp:02000446","sets":["4151:8699:4187:4189","4251:7205:7206:8773:7208"]},"author_link":["31295"],"control_number":"2000446","item_1693813220986":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1694497428290":{"attribute_name":"学位名","attribute_value_mlt":[{"subitem_degreename":"博士(理学)","subitem_degreename_language":"ja"}]},"item_1694497507610":{"attribute_name":"学位名（英）","attribute_value_mlt":[{"subitem_degreename":"Doctor of Philosophy in Science","subitem_degreename_language":"en"}]},"item_1694497573527":{"attribute_name":"学位授与機関","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_language":"ja","subitem_degreegrantor_name":"同志社大学"},{"subitem_degreegrantor_language":"en","subitem_degreegrantor_name":"Doshisha University"}],"subitem_degreegrantor_identifier":[{"subitem_degreegrantor_identifier_name":"34310","subitem_degreegrantor_identifier_scheme":"kakenhi"}]}]},"item_3_alternative_title_2":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"光照射下におけるチオエーテルの酸化とアルケンの電気化学的変換に関する研究","subitem_alternative_title_language":"ja"},{"subitem_alternative_title":"ヒカリ ショウシャカ ニオケル チオエーテル ノ サンカ ト アルケン ノ デンキ カガクテキ ヘンカン ニカンスル ケンキュウ","subitem_alternative_title_language":"ja-Kana"}]},"item_3_date_granted_27":{"attribute_name":"学位授与年月日","attribute_value_mlt":[{"subitem_dategranted":"2024-03-22"}]},"item_3_description_12":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"この博士論文では、有機合成における光や電気エネルギーの利用のための新しい手法が報告されている。第1章では、光触媒を使用せずに、チオアニソール誘導体のC-H結合を活性化する直接光照射法が明らかにされ、硫黄含有有機化合物の誘導化が可能となったことを述べられている。第2章では、チオアニソール誘導体、マレイミド誘導体、および二酸化チタン粒子を用いた、可視光下での硫黄含有六員環化合物の新規合成法が述べられている。第3章では、UVで照射下でのチオアニソールの好気的酸化が詳細に調べられ、トリフルオロエタノールを溶媒とすると、単一生成物としてスルフォキシドが得られることを明らかにしている。また、ホウ素ドープダイヤモンド陽極を用いて炭酸イオンから過炭酸イオンを生成し、マンガン錯体触媒とともに水を酸素源として用いてアルケンのエポキシ化反応を行う手法についても論じられている。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"In this doctoral thesis, novel methodologies for utilizing light and electrical energy in organic synthesis are reported. Chapter 1 unveils a direct photoirradiation approach for activating C-H bonds in thioanisole derivatives, enabling the derivatization of sulfur-containing organic compounds without photocatalysts. Chapter 2 introduces a visible light-mediated synthesis of sulfur-containing six-membered organic compounds with carbon-carbon double bonds using thioanisole derivatives, maleimide derivatives, and titanium dioxide particles. Chapter 3 investigates the aerobic oxidation of thioanisole under UV irradiation, revealing that sulfoxide can be selectively obtained using trifluoroethanol as the solvent. Additionally, the thesis explores the generation of percarbonate from carbonate ions using a boron-doped diamond anode and the epoxidation of alkenes using water as the oxygen donor with a manganese complex catalyst.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_18":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_dissertation_number_28":{"attribute_name":"学位授与番号","attribute_value_mlt":[{"subitem_dissertationnumber":"甲第1348号"}]},"item_3_relation_16":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"BD10264809","subitem_relation_type_select":"NCID"}}]},"item_3_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"掲載刊行物所蔵情報へのリンク ／ Link to 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Donor-Acceptor Complex","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Annulation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Charge Transfer","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Photocatalysis","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Radical Reaction","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Thioanisole Oxidation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Boron-Doped Diamond","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Electrochemical Epoxidation","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Manganese Salen Complex","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Parcarbonate","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"},{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"doctoral thesis","resourceuri":"http://purl.org/coar/resource_type/c_db06"}]},"item_title":"Studies on thioether oxidation under light irradiation and electrochemical transformation of Alkenes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Studies on thioether oxidation under light irradiation and electrochemical transformation of 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