{"created":"2023-07-27T07:30:28.260021+00:00","id":1161,"links":{},"metadata":{"_buckets":{"deposit":"346843ba-448e-41a0-a997-9afcb9289b8a"},"_deposit":{"created_by":21,"id":"1161","owners":[21],"pid":{"revision_id":0,"type":"depid","value":"1161"},"status":"published"},"_oai":{"id":"oai:doshisha.repo.nii.ac.jp:00001161","sets":["4151:8699:4190:4191","4251:7209:7210:8775:7211"]},"author_link":["2565"],"item_1693813220986":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_1694497428290":{"attribute_name":"学位名","attribute_value_mlt":[{"subitem_degreename":"博士(工学)","subitem_degreename_language":"ja"}]},"item_1694497507610":{"attribute_name":"学位名（英）","attribute_value_mlt":[{"subitem_degreename":"Doctor of Philosophy in Engineering","subitem_degreename_language":"en"}]},"item_1694497573527":{"attribute_name":"学位授与機関","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_language":"ja","subitem_degreegrantor_name":"同志社大学"},{"subitem_degreegrantor_language":"en","subitem_degreegrantor_name":"Doshisha University"}],"subitem_degreegrantor_identifier":[{"subitem_degreegrantor_identifier_name":"34310","subitem_degreegrantor_identifier_scheme":"kakenhi"}]}]},"item_3_alternative_title_2":{"attribute_name":"その他（別言語等）のタイトル","attribute_value_mlt":[{"subitem_alternative_title":"ルテニウムが触媒する\"Borrowing Hydrogen\"に基づく有機反応に関する研究","subitem_alternative_title_language":"ja"},{"subitem_alternative_title":"ルテニウム ガ ショクバイ スル Borrowing Hydrogen ニモトズク ユウキ ハンノウ ニカンスル ケンキュウ","subitem_alternative_title_language":"ja-Kana"}]},"item_3_date_granted_27":{"attribute_name":"学位授与年月日","attribute_value_mlt":[{"subitem_dategranted":"2014-03-22"}]},"item_3_description_12":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"特異なルテニウムが触媒する\"Borrowing hydrogen\"のコンセプトに基づく有機反応を開発した。まず、Ru/JOSIPHOS触媒を用いて、1,2-ジオールとアミンの反応から光学活性β-アミノアルコールを最高99%収率ならびに77% eeで得ることに成功した。本反応は新規であり、その反応機構についても明らかにした。さらに、RuCl2(PPh3)3/DPEphos/K3PO4を組み合わせた触媒を用いることで、アルコールをアルキル化剤に用いるインドールの3位選択的アルキル化反応を達成した。高効率かつ広いタイプの基質に適用できる。","subitem_description_language":"ja","subitem_description_type":"Abstract"},{"subitem_description":"Several novel ruthenium-catalyzed \"borrowing hydrogen\"-based organic reaction has been developed. For very first time optically active β-amino alcohols can be sinthesized directy by reaction of 1,2-diol and coressponding amine under Ru/JOSIPHOS catalysis in up to 99% yield and 77% ee. Since this reaction is very new, intensive investigation of the reaction mechanism was also carried out. Meanwhile, combination of RuCl2(PPh3)3/DPEphos/K3PO4 was found to be effective catalyst for alkylation of indole with alcohol as an alkylating reagent. This catalysis was highly reactive to give the corresponding alkylated indole in excellent yield for almost all types of indoles and alcohols substrates.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_description_18":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_3_dissertation_number_28":{"attribute_name":"学位授与番号","attribute_value_mlt":[{"subitem_dissertationnumber":"甲第673号"}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.14988/di.2017.0000016180","subitem_identifier_reg_type":"JaLC"}]},"item_3_relation_16":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"BB18762747","subitem_relation_type_select":"NCID"}}]},"item_3_relation_17":{"attribute_name":"関連サイト","attribute_value_mlt":[{"subitem_relation_name":[{"subitem_relation_name_language":"ja","subitem_relation_name_text":"掲載刊行物所蔵情報へのリンク ／ Link to Contents"}],"subitem_relation_type":"isFormatOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doors.doshisha.ac.jp/opac/opac_link/bibid/BB12905970/?lang=0","subitem_relation_type_select":"URI"}}]},"item_3_text_8":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_language":"ja","subitem_text_value":"生命医科学研究科"}]},"item_3_text_9":{"attribute_name":"著者所属（英）","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Graduate School of Life and Medical Sciences"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Putra, Anggi Eka","creatorNameLang":"en"}],"nameIdentifiers":[{},{},{}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2014-07-04"}],"displaytype":"detail","filename":"k673.pdf","filesize":[{"value":"348.9 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"要旨/abstaract","objectType":"abstract","url":"https://doshisha.repo.nii.ac.jp/record/1161/files/k673.pdf"},"version_id":"dff0b1c7-7dbb-41a6-a7c3-cb7d6a822eec"},{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2014-07-30"}],"displaytype":"detail","filename":"zk673.pdf","filesize":[{"value":"1.8 MB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"zk673.pdf","objectType":"fulltext","url":"https://doshisha.repo.nii.ac.jp/record/1161/files/zk673.pdf"},"version_id":"25f22766-7f3e-47d5-99e1-59e38bc5289a"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"β-amino alcohol","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Borrowing Hydrogen","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Ruthenium catalysis","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Alcohol","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Indole","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"doctoral thesis","resourceuri":"http://purl.org/coar/resource_type/c_db06"}]},"item_title":"Studies on ruthenium-catalyzed \"Borrowing Hydrogen\"-based organic reactions","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Studies on ruthenium-catalyzed \"Borrowing Hydrogen\"-based organic reactions","subitem_title_language":"en"}]},"item_type_id":"3","owner":"21","path":["4191","7211"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2014-07-04"},"publish_date":"2014-07-04","publish_status":"0","recid":"1161","relation_version_is_last":true,"title":["Studies on ruthenium-catalyzed \"Borrowing Hydrogen\"-based organic reactions"],"weko_creator_id":"21","weko_shared_id":-1},"updated":"2024-02-06T04:44:52.988208+00:00"}